The One Where Paul's The Man - S6-E22
Visible crew/equipment: In the scene where Rachel is trying to hide Ross from Paul, when he's about to go into Paul's bedroom after he says "Did you really hear a bear?", look at the window behind Rachel when the shot is on her. You can see a large light reflected in the glass and it moves slightly (not just in conjunction with the camera, it moves before the camera shifts).
Answer: The painting doesn't have a name, and if it does it is never mentioned in this episode.