The One Where the Monkey Gets Away - S1-E19
Other mistake: When Rachel's watching the soap opera on TV while babysitting Marcel, she and Marcel are sitting in the middle of the couch, but in the closeup of Dr. Francis we can see the reflection of the empty couch at the bottom of the TV screen.
Answer: The statements that she's contradicting (that it is common, it happens to every guy, and it's not a big deal), are the things that a woman commonly says to a man who is suffering from erectile difficulty, typically to assuage his bruised ego. However, most men do not believe that these statements are true, as evidenced by Chandler's outburst. He's so caught up in the proof that women are lying about it that he gives himself away.
Rooster of Doom