The Launch Acceleration - S5-E23
Continuity mistake: In the scene where Sheldon is scooping spaghetti onto his plate, he pauses with the spoon in the serving dish. Shot cuts to Amy and the spoon is still in the serving dish. When shot cuts back to Sheldon the spoon is being held over his plate. Shot cuts back to Amy and the spoon is back in the dish.
Answer: Because Raj's selective mutism seems to be caused by women that Raj sees (on some sort of conscious or subconscious level) as a potential sexual partner. An attribute that wouldn't apply to either his sister or mother.