Audio problem: Right after Ross and Rachel leave the wedding chapel, Joey and Phoebe rush in. Joey is saying "C'mon, Pheebs, hurry, hurry." and she is saying "Okay, okay." However, neither one is moving their lips. (00:00:25)
The One Where Ross Hugs Rachel - S6-E2
Audio problem: In the pre-theme-song scene, with Phoebe and Ross talking outside the coffeehouse, when Phoebe sends Rachel away in the cab for the second time the sound of the tyres screeching starts while the cab is still stationary.
The One Where Ross Got High - S6-E9
Audio problem: When Ross and Joey go into the bedroom, you can hear the duck in the background, even though the chick and the duck should be in the other apartment and aren't even in this episode. (00:12:53)
The One With The Routine - S6-E10
Audio problem: When Ross has finished telling everyone the story of the dreidel, we cut to Monica and Chandler's reaction shot which shows Ross' mouth moving even though he is not talking. (00:01:30)
The One With The Apothecary Table - S6-E11
Audio problem: When Phoebe puts her feet up on Ross' apothecary table, Ross asks her not to put her feet up on his "new...old sheet." During the pause right after he says "new," there's a cut to a different angle and you can see his mouth form the words "old sheet." Then it cuts to a different angle and we actually see and hear Ross say "old sheet." (00:12:05)
The One With The Proposal, part 2 - S6-E25
Audio problem: In the pizza place, after Chandler tells Monica to "put down [her] copy of The Rules..." you hear Monica say, "You know what. I gotta go" when her lips aren't moving. (00:04:26)