A Star is Born-Again - S14-E13
Audio problem: When Lenny talks about selling Sara's autograph on eBay, his lips don't match what he says.
A Star is Born-Again - S14-E13
Audio problem: When Homer tells Ned "Flanders, I'm always interested in talking about free milk. And if there's cookies involved, so much the better", his mouth is not in sync with his voice.
Answer: I'm not sure if this is the one you're thinking of, but an episode of "Ray Bradbury Theatre," called "A Sound of Thunder," dealt with a similar matter: a group of hunters travel back in time to hunt dinosaurs, only to find things have changed when they get back because someone stepped on a butterfly.
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