Sleuthing With the Enemy - S3-E8
Revealing mistake: When Cole / Belthazar grabs Phoebe to use her as a hostage, you can see, very obviously, that he doesn't pull her. Phoebe actually steps in front of him willingly, despite the look of fear on her face.
Sleuthing With the Enemy - S3-E8
Revealing mistake: When Phoebe throws the potion at Cole's coat, the vial doesn't shatter, even though it sounds like it. Watch closely, and you'll see the purple, unbroken vial bounce off the coat and away out of shot without any of the potion touching the coat.
Sleuthing With the Enemy - S3-E8
Other mistake: When Piper puts the Belthazor flesh into the Belthazor vanquishing potion, she is the only one that gets "blasted" back even though she is the one standing farthest away from the stove and the potion.
Sleuthing With the Enemy - S3-E8
Other mistake: Cole is supposed to be one of the most powerful demons alive, but a small cut from Piper weakens him to the point where he can't even shimmer or keep up his "Cole" appearance.
Sleuthing With the Enemy - S3-E8
Audio problem: When Phoebe fights with Krell in the mausoleum, the vial containing the Belthazor vanquishing potion is heard smashing, but after Krell is vanquished, Phoebe picks up an unsmashed vial and uses it to stage Cole's escape.
Chosen answer: Her agent/manager negotiated a special billing as part of her contract. It distinguishes her from the rest of the cast, probably when she became a producer on the show.
JC Fernandez