Bloodlines - S7-E22
Continuity mistake: When Jason and Picard are having a conversation in the holodeck, Jason says "I remember her telling me about all the boys and girls who didn't have anyone to care for them" while looking in the opposite direction of where Picard is sitting. The camera angle changes to a close-up and Jason now has his head turned slightly towards Picard.
Chosen answer: The uniform does indeed change colour. It may be due to the need for a green screen in part, or perhaps some lighting altering our perception. That being said, it certainly looks green at the start, blue thereafter.
The show has been done in HD now and not sure if they fix this problem.
Dan23