Revealing mistake: Before Phoebe agrees to carry Frank and Alice's' triplets, she already has a baby bump.
The One With The Fake Party - S4-E16
Continuity mistake: When Rachel is in her bedroom dressed as a cheerleader with Joshua, the sleeve of her sweater on her right arm keeps moving up and down. (00:15:00)
The One With Ross's Wedding, part 1 - S4-E23
Plot hole: The wedding is threatened because Ross, Emily, and Monica discover that the location has been torn down a few days early. However, when one plans an event, especially a wedding, one puts down a deposit to hold the location, signs a contract, and has all of that in writing. The church would not have allowed the tear-down to happen early as they'd be in breach of contract for accepting money and then allowing the church to be torn down before the wedding. And if they had broken the contract, Monica would have been screaming about it and demanding a refund.
The One With Rachel's Crush - S4-E13
Continuity mistake: At the start of this episode when Rachel comes in, you can see a bit of wooden floor by the door (carpet's visible in other shots). However, Monica doesn't pull up the carpet until later in the episode, after the apartment's tidier. (00:02:10)
The One With The Worst Best Man Ever - S4-E22
Other mistake: Given her vegetarianism, and her disdain for fur in another episode, there's no way Phoebe would have wanted a pair of leather pants.
Suggested correction: It's your opinion that Phoebe wouldn't have wanted leather pants, but that's not true of all vegetarians. Natalie Merchant was known for saying she was a vegetarian but still wore leather shoes. I was a vegetarian who would never have worn fur and still wore leather shoes.
The One With The Fake Party - S4-E16
Continuity mistake: While Joey spins the bottle and it keeps pointing to Emily, in the shots facing Ross the door behind him goes back and forth from being either closed or wide open, depending on the angle of the shot.
The One With The Fake Party - S4-E16
Continuity mistake: After Rachel spins the bottle and it points to Joshua, when she crawls toward him on her hands and knees the bottle is in front of her knees in the shots facing her, but in the shot facing Joshua the bottle is at her side, near her foot.
The One With The Embryos - S4-E12
Character mistake: Both lightning rounds at the end of the quiz are significantly longer than the 30 seconds that Ross claims they are. (Even though he is supposedly using a stopwatch to time them.) The guys' lightning round is actually 43 seconds long, and the girls' lightning round is 45 seconds long. (00:14:20)
The One With The Ballroom Dancing - S4-E4
Revealing mistake: During the end bit, before we get to see Phoebe when she is being interviewed at Lara and Jeni's Massage, if you look closely at the name of the massage parlor, you'll see that, although the camera shakes and bumps, the words stay on the very same spot on the screen. Obviously the canopy was blank and the name was digitally added later.
The One With All The Wedding Dresses - S4-E20
Continuity mistake: When Rachel suggests to Joshua that they should get married, he says "What?", and his hands are out in front of him. The camera cuts to a wide shot and his hands are now on his thighs. Cut back to Joshua and his hands are now out in front of him with his fingers interlocked.
The One With Chandler In A Box - S4-E8
Visible crew/equipment: After Joey tells Chandler he's going to his folks and might stay there for a few days while looking for an apartment, just as Joey retrieves his keys from the shelf, a crew member wearing a black shirt and white pants is visible on the left side of the screen. (00:08:40)
The One With The Free Porn - S4-E17
Other mistake: 10:50pm boarding and departure, but it is broad daylight outside. (00:09:25)
The One With Ross's Wedding, part 2 - S4-E24
Audio problem: Toward the end of the episode Ross' Dad and Emily's dad are arguing. Ross comes between them and you can hear the audio saying"From now on everybody gets along!" But it does not match up with the movement of Ross' lips.
The One With The 'Cuffs - S4-E3
Continuity mistake: Rachel is telling Chandler to break off his relationship with Joanna, who had walked through the room and went into Chandler's bedroom, shutting the door. By the end of the conversation between Chandler and Rachel, the door is open but no one has entered or left the room.
The One With The Free Porn - S4-E17
Continuity mistake: In the scene where Phoebe tells the gang about her "Relaxitaxi" idea the position of Chandler's left arm changes between shots. In the frontal shots it's lying the back of the chair and in the shots from behind it's wrapped around Monica's shoulder.
The One With All The Haste - S4-E19
Factual error: The guys are gone for a single night, watching the Knicks game. (You can tell this because they talk about how "we can go see the game tonight," and when they get back everyone's wearing the same clothes as that conversation.) When they get back, both apartments are completely switched back: the large, heavy furniture is replaced, the posters are re-hung, etc. Even if they were gone from, say, 6 p.m. to midnight or so, there is no way that Rachel and Monica would be able to make that transition in that kind of time.
The One With The Embryos - S4-E12
Character mistake: When they are about to start the game, Ross declares that "the first team to answer the most questions wins." This is a nonsensical statement. By that logic, the first team to answer a question correctly would be the winner. It should be either the team that has correctly answered the most questions at the end of the game wins, or the first team to correctly answer an X number of questions.
Suggested correction: While it's a weird way for him to say it, he starts by saying "each team will answer ten questions", so no, the first team to answer a question wouldn't win.
Yes, he qualified that it was a 10-question game, and we as the audience understand going in how the winner is decided. It's just the way he declared how the winner would be decided didn't make sense. It would be like watching an NBA game, and before tipoff, the crew chief tells both teams that the first team to score the most baskets wins. We know what the rules of an NBA game are, but the referee makes a nonsensical statement all the same.
Except there's so many variations of how a team can win a game; best 3 out of 5, win by 2, or a game can even end in a tie. Since this isn't a professional sport where all the players know how a game ends, Ross is basically saying after 10 rounds, if there is a tie, it will go to sudden death with the team with the first correct answer winning, just not in so many words.
The One With Chandler In A Box - S4-E8
Visible crew/equipment: When Chandler is climbing out of the box, you can see the bottom of the set spotlight right above the bathroom door. (00:20:35)
The One With The Embryos - S4-E12
Other mistake: Phoebe takes a positive pregnancy test right after she gets implanted with the embryos. There's no test in the world that can tell that fast if someone is pregnant - even the best tests take at least a week after conception.
Suggested correction: Phoebe explains before she takes the first pregnancy test that her body's "always been a little faster than Western medicine". It's a deliberate joke.
A deliberate joke it may be, but we all know Phoebe believes a lot of silly things, and this is one of them. It really didn't make sense for her to get a positive result that fast.
The One With Ross's Wedding, part 2 - S4-E24
Audio problem: When the wedding officiant says "take thee, Ross" his lips don't move. (00:20:35)