The One With All The Haste - S4-E19
Revealing mistake: When they are using cards to bet on the Knicks tickets, watch Joey carefully as he goes to reshuffle the pack from behind the arm of the chair. It's obvious that there are two decks, and he is in fact switching them over. (00:13:40)
Answer: The statements that she's contradicting (that it is common, it happens to every guy, and it's not a big deal), are the things that a woman commonly says to a man who is suffering from erectile difficulty, typically to assuage his bruised ego. However, most men do not believe that these statements are true, as evidenced by Chandler's outburst. He's so caught up in the proof that women are lying about it that he gives himself away.
Rooster of Doom