The One With a Chick. And a Duck. - S3-E21
Visible crew/equipment: Monica is talking to Pete in the diner when he gets back from Japan. If you look at the floor at Monica's end of the counter at the very beginning of the scene, you can see the mat that is there to protect her when she falls over later. (00:02:35)
Answer: The statements that she's contradicting (that it is common, it happens to every guy, and it's not a big deal), are the things that a woman commonly says to a man who is suffering from erectile difficulty, typically to assuage his bruised ego. However, most men do not believe that these statements are true, as evidenced by Chandler's outburst. He's so caught up in the proof that women are lying about it that he gives himself away.
Rooster of Doom