The One With Monica and Chandler's Wedding, Part 2 - S7-E24
Revealing mistake: At the point in the ceremony where Joey forgets the rings, the camera pans out and you see Chandler step sidewards to get the ring from Ross, and Monica step sidewards to get the ring from Rachel and Phoebe. As Monica moves, her dress slides across and one of her feet is revealed; it has what looks like a brown boot or heavy brown shoe on it. (00:20:05)
Answer: The statements that she's contradicting (that it is common, it happens to every guy, and it's not a big deal), are the things that a woman commonly says to a man who is suffering from erectile difficulty, typically to assuage his bruised ego. However, most men do not believe that these statements are true, as evidenced by Chandler's outburst. He's so caught up in the proof that women are lying about it that he gives himself away.
Rooster of Doom