The One With Joey's New Brain - S7-E15
Character mistake: After Susan Sarandon slaps Joey the first time, after he tells her that her character is dying on DOOL, she turns away and right before she is off camera she smiles, instead of maintaining her anger. (00:06:05)
Answer: The statements that she's contradicting (that it is common, it happens to every guy, and it's not a big deal), are the things that a woman commonly says to a man who is suffering from erectile difficulty, typically to assuage his bruised ego. However, most men do not believe that these statements are true, as evidenced by Chandler's outburst. He's so caught up in the proof that women are lying about it that he gives himself away.
Rooster of Doom