The One With Joey's New Brain - S7-E15
Other mistake: In the scene where Phoebe and Rachel are talking in Phoebe's apartment and Tom is waiting at the door, after Phoebe says "you are such a good friend", we hear someone say Tom, meaning its Tom's turn to talk. Extended episode only. (00:20:55)
Answer: The statements that she's contradicting (that it is common, it happens to every guy, and it's not a big deal), are the things that a woman commonly says to a man who is suffering from erectile difficulty, typically to assuage his bruised ego. However, most men do not believe that these statements are true, as evidenced by Chandler's outburst. He's so caught up in the proof that women are lying about it that he gives himself away.
Rooster of Doom