The Matrimonial Momentum - S9-E1
Continuity mistake: In the first half of the episode while in Las Vegas, Penny's hair is short; however, later in the episode when she is back in the apartment speaking with Sheldon, her hair is much longer, albeit tied back in a bun, but very obviously much longer and a very different color. The scene from Las Vegas to her apartment was less than 24 hours apart and would have been impossible for her hair to have grown so much.
Answer: Because Raj's selective mutism seems to be caused by women that Raj sees (on some sort of conscious or subconscious level) as a potential sexual partner. An attribute that wouldn't apply to either his sister or mother.