The Locomotive Manipulation - S7-E15
Continuity mistake: At the end of the episode when Lennard asks Sheldon about his train ride, he says that he kissed Amy on the lips, and says that it tasted like the brownies that they had that for dessert. But they were eating a tart of some type, with a shortbread crust. No brownies were on the table.
Answer: Because Raj's selective mutism seems to be caused by women that Raj sees (on some sort of conscious or subconscious level) as a potential sexual partner. An attribute that wouldn't apply to either his sister or mother.