The Conscience of the King - S1-E14
Revealing mistake: As Kirk and Lenore leave the cocktail party to walk around outside, they stop to talk. From Kirk's perspective, he is to the left of Lenore, enough to see what should be in view ahead of him. Only seconds later when she leans in to kiss him does he notice Dr. Leighton lying next to some rocks. She was not obscuring his view before. Why didn't Kirk see this while they first started talking? (00:10:36)
Answer: Kirk was getting his physical and Dr. McCoy probably turned off communications, because if he hadn't, Kirk would have left and headed straight for the bridge, leaving McCoy irritated.