All Good Things... (2) - S7-E26
Visible crew/equipment: Captain Picard joins the poker game and Data asks the Captain if he wants to deal. Picard says "Thank you Mr. Data." Riker sits down, and just before Captain Picard starts saying "Actually..." a camera or other bit of equipment briefly pops into shot behind Riker.
Answer: Yes. The doors to the holodecks can be locked when in use by anyone aboard the Enterprise so they couldn't be disturbed. However, high ranking officers like Captain Picard could override the doors as it's seen that overrides are in use even for the crews quarters. Even Barclay, when he's indulging in one of his fantasies could have the doors to the holodeck unlocked by an override code.