Revealing mistake: When Jonathan assists Buffy at the beginning of the episode, he enters through the glass ceiling of the mausoleum, which shatters into squares. Although the audio is the sound of glass shattering, the pieces of "glass" flutter down, revealing that the squares are paper - simply for the safety of the actor during the stunt. (00:05:00)
Once More, With Feeling - S6-E7
Revealing mistake: The knives Giles throws during Buffy's training are a very poor CGI job if you watch it in slow mo. All three knives Giles takes off the wall are identical, with a broad curved blade and a plain black handle. The first one has a transparent blade as it flies toward Buffy, then we hear it bounce off the far wall and it's way out of scale for the distance. The second knife has a diamond-patterned grip instead of a plain one. The third knife conveniently spins in midair for a second so Buffy can kick it out of the way. (00:30:35)
Revealing mistake: Towards the end, when Buffy stabs Faith, there is no blood whatsoever.
Revealing mistake: When Buffy breaks into the locker, the locker is already damaged. Probably from a previous take.
Suggested correction: Watching the scene, the only real damage is a slight dent that isn't all that close to the lock (she basically punches out the lock to open it). And to be perfectly honest, a dented locker isn't out of the ordinary for a high school. I saw plenty of dented, bent and damaged locker doors all the time back in high school. It's entirely probable that it is damaged from a previous take, but I think it's also within that sort-of realm of possibility (since like I said, dented lockers aren't out of the ordinary) that it might not be considered a mistake. I'll leave it up to people's votes.
Revealing mistake: When Buffy and Angel are sword-fighting, the camera pans up and to the side, you can see David Boreanaz's stunt double. His hair line is farther back then David Boreanaz's.
Revealing mistake: Near the end of the episode when the Mayor releases the vampire from his cage and lets him cut his head in half, you can tell that the Mayor's head is a still image when it fixes itself. The expression on his face doesn't change at all and looks completely unrealistic.
Revealing mistake: When Spike, Xander, Anya and the Buffybot are attacked by vampires in the cemetery, the grass for the cemetery moves underneath the vampires' feet as if it were a carpet. The cemetery was a sound stage and not an actual cemetery.
Revealing mistake: When the Gentlemen are chasing Tara in Stevenson Hall, in the first hallway two Gentlemen are floating down the corridor and you can tell they're on wires because the one on the screen's left "jumps" a little as if his wires got snagged.
Revealing mistake: Right at the beginning of the episode, Buffy is sat outside with Willow and Willow is levitating a pencil. The pencil is obviously CGI as it stands out from the rest of the picture and doesn't cast a shadow. It also disappears from view whenever there is a side-angle shot of Willow.
I Was Made To Love You - S5-E15
Revealing mistake: When Giles pushes Spike into the cabinet at the magic shop, you can see Spike's reflection in the glass of the cabinet's doors. But Spike is a vampire and therefore should have no reflection.
Revealing mistake: When Buffy is fighting the vampires that are trying to resurrect The Master, at one point she is grabbed from behind by a male vampire and kicks a female vampire in a green top twice (right after Absalom shouts "The sacrifices! Stop them!"). If you watch closely, both of the kicks miss the vampire, revealing that the fight was choreographed. The punch that she delivers to the male vampire afterwards also looks fake.
Nightmares - S1-E10
Revealing mistake: When Willow opens the door to the basement to look for Buffy, the shot looking up the basement's staircase shows Willow's shadow on the inside of the door. In the previous shot when she opened the door, it opens towards a wall and a staircase to the second floor. But there is no light source coming from the wall or the staircase, giving the impression that the basement was filmed on a separate set.
Revealing mistake: Watch the shot of Glory as she is hit by the truck at the beginning of the episode (easier to see in slow-mo/frame-by-frame). She isn't hit by the truck at all. It goes right past her. A simple optical illusion used in filmmaking for decades.
Revealing mistake: Both the good and evil Willows' faces are barely seen onscreen at the same time due to them being played by the same actress, but when they occasionally are the good Willow stands out from the picture more than the evil Willow. She must have been filmed separately from the good Willow and edited in later.
Revealing mistake: When evil Willow licks good Willow's neck the neck that you see is a lot longer than either of theirs. Since both Willows' faces cannot be filmed at the same time a body double must have been used for this shot.
Revealing mistake: In the beginning of the episode, when Buffy stakes the vampire that she beats up for a long time, watch when she lifts the stake. The hole in the vampire's chest is a solid 8" below where she actually hit him with the stake. (It's an effects shot, so somehow, they just didn't line up).
Revealing mistake: When Willow says "The usual " at the beginning of the episode and it cuts to Buffy landing on the ground, you can briefly but see the stunt woman playing Buffy's face in the first shot for a solid second or two. That definitely isn't Sarah Michelle Gellar.