The One With Rachel's Crush - S4-E13
Other mistake: Monica supposedly single-handedly changed over the guys' apartment from carpet to polished hardwood in two days. There's no way that someone of her size could have moved all that furniture solo (Rachel didn't help since she's totally surprised), stripped off all the carpet, sanded the wood, stained the wood, let it dry, and then replaced all the furniture, in two days.
Answer: The statements that she's contradicting (that it is common, it happens to every guy, and it's not a big deal), are the things that a woman commonly says to a man who is suffering from erectile difficulty, typically to assuage his bruised ego. However, most men do not believe that these statements are true, as evidenced by Chandler's outburst. He's so caught up in the proof that women are lying about it that he gives himself away.
Rooster of Doom