The One with All the Poker - S1-E18
Revealing mistake: When Rachel is doing the shuffling trick, it is clear that it is a trick deck. The cards, whilst flying from one hand to the other, change the angle of flight in mid-air, and some of them even move backwards as she moves her hands further apart from each other. This could only happen if the cards were connected to each other. (00:13:20)
Answer: The statements that she's contradicting (that it is common, it happens to every guy, and it's not a big deal), are the things that a woman commonly says to a man who is suffering from erectile difficulty, typically to assuage his bruised ego. However, most men do not believe that these statements are true, as evidenced by Chandler's outburst. He's so caught up in the proof that women are lying about it that he gives himself away.
Rooster of Doom