The One With Phoebe's Wedding - S10-E12
Revealing mistake: Just before we see everyone setting the wedding up outside, there is a sweep shot of the city with snow falling. It's very obvious that this snow is added digitally and it's very badly done. There is no snow on any of the buildings, and there is no snow hitting the surface of the water. (00:20:50)
The One With Phoebe's Wedding - S10-E12
Revealing mistake: At the wedding, none of the snow melts when it has been sitting on people for several minutes. Occasionally when it gets brushed off clothes it just sticks to hands and sleeves, again for several minutes without melting. (00:21:15)
Answer: The statements that she's contradicting (that it is common, it happens to every guy, and it's not a big deal), are the things that a woman commonly says to a man who is suffering from erectile difficulty, typically to assuage his bruised ego. However, most men do not believe that these statements are true, as evidenced by Chandler's outburst. He's so caught up in the proof that women are lying about it that he gives himself away.
Rooster of Doom