The One Where Ross Got High - S6-E9
Plot hole: Monica is trusting Rachel to make a traditional English trifle and being a top chef (or an even averagely intelligent human being) she would know what ingredients are used in one. So there's no way she could have missed Rachel cooking beef with peas and onions during the cooking process. Rachel's cooking it right there in Monica's kitchen while everyone else is there!
Answer: The statements that she's contradicting (that it is common, it happens to every guy, and it's not a big deal), are the things that a woman commonly says to a man who is suffering from erectile difficulty, typically to assuage his bruised ego. However, most men do not believe that these statements are true, as evidenced by Chandler's outburst. He's so caught up in the proof that women are lying about it that he gives himself away.
Rooster of Doom