The One With The Birth Mother - S10-E9
Plot hole: David Schwimmer is 6'2" tall and Jennifer Aniston is 5'6". There is no way that clothes that fit Rachel would also fit Ross. When he puts on the clothes that Rachel bought it's obviously not Rachel's size. If it really were, it would be a lot tighter and shorter (Ross could probably wear it belly free).
Answer: The painting doesn't have a name, and if it does it is never mentioned in this episode.