Audio problem: When the cop is telling Charles that he is going to circle the block, in the wide shot, his lips don't match the words. This happens a couple of minutes before Charles dumps the car into the river.
Derailed (2005)
1 audio problem - chronological order
Directed by: Mikael Hafstrom
Starring: Jennifer Aniston, Clive Owen, Vincent Cassel, Melissa George, Addison Timlin
Revealing mistake: When Charles Shine arrives at the bus station in the pouring rain, the background on all sides of him can be seen to be pure sunshine and dry land. It is obvious that a rain machine covering a VERY SMALL area was being used.
Charles Schine: Please, just take the money.
Philippe LaRoche: Chuck, I already took your money. You see this? This was your money, and I took it. Now it's mine.
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Answer: I assumed that that Charles Shine did not have time to return the money to the work account before his boss discovers it is gone because the banks would have been closed when he was at the hotel and retrieved the briefcase with the $100,000. Granted, prior to this he asks his boss for a check for the commercial expense, so it might have made more sense to ask for a transfer earlier because a check implies that he did not signing for funds and could not have embezzled the funds. How he stole it if he did not have access to the account, I do not know.