The Wedding - S5-E1
Revealing mistake: After Scorpion causes the chandelier to fall onto Spider-Man, the camera pans to the right and Scorpion appears out of thin air onto the screen.
Secret Wars, Chapter 3: Doom - S5-E11
Revealing mistake: After Dr. Doom has stolen the Beyonder's powers, he demonstrates the powers to Ben Grimm in his throne room by teleporting Red Skull, Dr. Octopus and Smythe off the planet. Next he teleports all the heroes to his throne room, and the shot of all the heroes is from two episodes prior when all the heroes were battling the Lizard. This shot of the heroes also includes Ben Grimm in form as the Thing, meaning Ben Grimm was in two places at once. Spider-Man, the Lizard and the rest of the Fantastic 4 were also already prisoners in Doom's castle, which means they were all in two places at once as well.
Spider Wars, Chapter 2: Farewell Spider-Man - S5-E13
Revealing mistake: When Spider-Man is web-slinging with Stan Lee, they pass the same group of buildings twice, revealing it to be recycled animation.
Answer: Yes. Many things that would have been in the sixth season would have had Norman Osborne returning from limbo and reclaiming the title of the Green Goblin, Richard Fisk, the son of "The Kingpin" Wilson Fisk would return as a crime lord known as "The Rose", Ghost Rider would have appeared to help Spider-Man stop Dormammu from returning to Earth and Madame Web and Spider-Man would rescue Mary Jane from limbo.