The Justice League Recombination - S4-E11
Character mistake: Even with Penny and Zack the guys are one man short to be the original JLA because they they don't have the Martian Manhunter. If they used the same costumes in the previous year, they would have been three people short of the original line-up.
Answer: Because Raj's selective mutism seems to be caused by women that Raj sees (on some sort of conscious or subconscious level) as a potential sexual partner. An attribute that wouldn't apply to either his sister or mother.