How Green Was My Grass - S4-E24
Continuity mistake: Before this episode (and after as well) Darrin and Samantha give their address as 1164 Morning Glory Circle, however in this episode, when Darrin slams the door, the '9' in 192 on their address spins around to make 162, hence the angry neighbor at 162 saying that his grass was installed at the Stevens' by mistake.
Answer: Larry had been telling Darrin what it means psychologically that Samantha gave the coat away. Larry said giving it away meant she's happy being married but if she liked the coat it means she desires to be single and carefree. So when Darrin sees the coat, he immediately thinks Samantha doesn't want to be married and the fact that she twitched it means (in his mind) she wants to be a single, carefree witch again.
Bishop73