Tree House of Horror X - S11-E4
Other mistake: In "Desperately Xeeking Xena", at one point she approaches the Collector, who is about to get a light saber. We can see the back of the pouch that Xena is in, but the tape on the other side isn't visible, even though it is a transparent pouch.
Answer: I'm not sure if this is the one you're thinking of, but an episode of "Ray Bradbury Theatre," called "A Sound of Thunder," dealt with a similar matter: a group of hunters travel back in time to hunt dinosaurs, only to find things have changed when they get back because someone stepped on a butterfly.
Xofer