Which Prue Is It, Anyway? - S1-E16
Continuity mistake: While Phoebe explains the slam man training system Piper puts on Phoebe's boxing gloves, and when Prue says that demons don't play fair Piper playfully raises her left arm to Prue's forehead, but in the next shot facing Prue it's Piper's right arm that's raised. (00:04:00)
Which Prue Is It, Anyway? - S1-E16
Continuity mistake: When Prue goes up to cast the spell, Piper and Phoebe are downstairs and Piper's hair is down. When they hear the effects of the spell they run in to the attic and both say "Oh my god!" one after the other and Piper's hair is now slicked back in a ponytail.
Continuity mistake: In this episode, the sisters go back in time to late March 1975. On the family tree it says that Piper was born on August 7, 1973. So she would be 1 and 1/2 in March 1975. But she looks at least 2 years too old. (00:09:30)
When Bad Warlocks Go Good - S1-E18
Continuity mistake: Prue finds Brendan, as a warlock, over the corpse of Father Austin. He runs away and she pursues him. He insists that he "didn't hurt Father Austin. [He] found him like that." Prue counters, "Before or after you turned into a warlock?" His response is, "After. When I saw what [my brothers] did to him, I was crazed. The rage turned me into a warlock." So doesn't that mean that he found Father Austin before he turned into a warlock, not after? (00:17:55)
Suggested correction: He said after because Brendan has always been a warlock. He was born that way.
When Bad Warlocks Go Good - S1-E18
Continuity mistake: When Brendon is about to sacrifice the young woman he has the tip of the dagger touching her chest in one shot and in the next shot, when Prue breaks open the door, it is about six inches above her. Also, when the victim is talking to Andy she says that she felt the tip of the knife, that he was about to drive it into her, but he was stopped by three woman. (00:24:15)
Continuity mistake: After the Grimlock kidnaps the child getting the ball, Prue goes after it. But the demon opens a hole in the earth and jumps through it and it closes. Prue then reaches the spot where the Grimlock disappeared and she is surrounded by dead leaves and trees. Then it goes to another shot of Prue turning around. Suddenly the trees and dead leaves are gone and she is standing in an open area with green grass and no trees.
Continuity mistake: While Andy and Darryl are at the station talking about why Andy's been "walking around...like a zombie," Andy places a pencil behind his ear, but when it cuts to Inspector Blakely walking in behind Andy the pencil has vanished between shots, but it reappears again in the next shot. Then when Andy borrows the photograph of the knife, once again the pencil vanishes between the closeup and wideshot. (00:09:10)
Love Hurts - S1-E21
Continuity mistake: In this episode Leo specifically tells Prue, Piper and Phoebe not to touch the Darklighters arrow because it is poisonous however in future episodes/seasons, the Darklighter arrows are only poisonous to Whitelighters. (00:06:30)
Love Hurts - S1-E21
Continuity mistake: When Prue shoots the Darklighter arrow at Alec, he orbs out and the arrow sticks into the wall behind him. In the next shot, the arrow has disappeared. (00:25:45)
Love Hurts - S1-E21
Continuity mistake: Leo dies and then Piper heals him. In all future episodes it's made very clear that Leo's powers can't heal the dead.
Deja Vu All Over Again - S1-E22
Continuity mistake: At the end of the episode, Phoebe's hairstyle changes from tied back when talking to Piper in the kitchen, to down and re-done in the time from the kitchen to the front porch.