The One With All The Resolutions - S5-E11
Character mistake: In one of the scenes where Phoebe is teaching Joey guitar, she asks him to demonstrate the "Iceberg" chord. To refresh his memory, Joey refers to the chord as "G Sharp." In reality, the only way to play a G Sharp chord is with a barre chord, and as such the fingering is not exclusive to it.
The One With Ross's Sandwich - S5-E9
Character mistake: Joey tells Chandler and Monica that Rachel found the underwear in Monica's sofa. It was actually Phoebe who pulled them from the sofa and held them up.
Answer: The statements that she's contradicting (that it is common, it happens to every guy, and it's not a big deal), are the things that a woman commonly says to a man who is suffering from erectile difficulty, typically to assuage his bruised ego. However, most men do not believe that these statements are true, as evidenced by Chandler's outburst. He's so caught up in the proof that women are lying about it that he gives himself away.
Rooster of Doom