The One With The Routine - S6-E10
Continuity mistake: When the Snippy Guy is pointing out couples to go on the platforms next, he points to one couple with his left hand, while holding a clipboard in his right hand. In the very next shot he points to the next couple, but this time with his right hand while holding the clipboard in his left. (00:11:15)
Answer: The statements that she's contradicting (that it is common, it happens to every guy, and it's not a big deal), are the things that a woman commonly says to a man who is suffering from erectile difficulty, typically to assuage his bruised ego. However, most men do not believe that these statements are true, as evidenced by Chandler's outburst. He's so caught up in the proof that women are lying about it that he gives himself away.
Rooster of Doom