The One After Ross Says Rachel - S5-E1
Revealing mistake: When Phoebe phones Emily's step-mother to say she is Ross' doctor, she looks out the window behind Phoebe. The buildings are moving slowly from side to side. (00:04:10)
The One After Ross Says Rachel - S5-E1
Revealing mistake: When Chandler and Monica (and later Joey) are talking on the plane on the way back from London, the little display screen (showing a map of the Atlantic and coastlines) in front of Monica's seat shows the little grey plane indicating their position and direction. The plane is facing east, as though they are travelling towards London, but they are supposed to be flying back to New York. (00:14:45)
Answer: The statements that she's contradicting (that it is common, it happens to every guy, and it's not a big deal), are the things that a woman commonly says to a man who is suffering from erectile difficulty, typically to assuage his bruised ego. However, most men do not believe that these statements are true, as evidenced by Chandler's outburst. He's so caught up in the proof that women are lying about it that he gives himself away.
Rooster of Doom