Guess Who's Coming to Breakfast, Lunch and Dinner - S10-E1
Revealing mistake: Near the beginning when Al is looking for his magazines under Bud's bed, a large shadow of someone crosses over him showing someone in production crossed in front of the lighting.
Answer: It's implied that Steve filed for divorce since in s04e16, "You Gotta Know When to Hold 'Em", Marcy says that Steve is suing for alimony. Alimony is something that has to be requested when filing for divorce. Although the show doesn't spend time on the actual legal proceedings of their divorce.
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