The Bottom Line Is Murder - S3-E15
Continuity mistake: When the cop picks up the dirty ashtray he blows the ash away. In the close-up the ashtray is spotless as if it had been wiped with a cloth or if it were brand-new. First of all, no ash blew away, and second of all, a mere puff couldn't have cleaned it the way it looks.
Answer: In a flashback scene, it was shown that he had a violent temper, so it stands to reason that he finally killed her in a fit of rage.