Six Meetings Before Lunch - S1-E18
Character mistake: In this episode, the character Jeff Breckenridge meets with Josh to plan his Senate confirmation. When explaining what led him to be a civil rights lawyer, he tells how his great grandfather was captured into slavery, and "taken to New Guinea to be shipped to America". The character probably means Guinea, or Guinea Bisseau, or Equatorial Guinea, three places in the Western coast of Africa from which black slaves were sent to America. New Guinea, on the other hand, is half-the-world away, near Australia.
Chosen answer: A really annoying innate lack of sense. My friends and family say the same thing all the time, and I'm endlessly trying to correct them. I think people just don't know any better and (ironically) couldn't care less that they're speaking incorrectly.