Double, Double, Toil and Trouble - S4-E4
Continuity mistake: The laundry room is far too large to fit into the space it appears to occupy beside the Stephens' kitchen. (00:04:50)
Double, Double, Toil and Trouble - S4-E4
Revealing mistake: As Serena gets hit by the pie her real blonde hair shows underneath, also, she wears minimal make-up for the only time.
Answer: Larry had been telling Darrin what it means psychologically that Samantha gave the coat away. Larry said giving it away meant she's happy being married but if she liked the coat it means she desires to be single and carefree. So when Darrin sees the coat, he immediately thinks Samantha doesn't want to be married and the fact that she twitched it means (in his mind) she wants to be a single, carefree witch again.
Bishop73