Lisa's Pony - S3-E8
Other mistake: When Lisa rings Homer to tell him that she loves him, the shot of her talking is re-used from "Bart's Dog Gets an F." We can tell this because her cheeks inexplicably appear puffed up (in "Bart's Dog Gets an F" she had mumps).
Answer: I'm not sure if this is the one you're thinking of, but an episode of "Ray Bradbury Theatre," called "A Sound of Thunder," dealt with a similar matter: a group of hunters travel back in time to hunt dinosaurs, only to find things have changed when they get back because someone stepped on a butterfly.
Xofer