The War of the Simpsons - S2-E20
Continuity mistake: When Homer has caught General Sherman he beats it with an oar so that the oar snaps in two. Then suddenly Homer rows with both oars intact.
The War of the Simpsons - S2-E20
Revealing mistake: When Ned says "Crème de cassis" while describing what was in the drink he made. There are several animation errors in this shot. His head is disconnected from his body, and his nose disappears. Also, a part of his face is missing between his fingers while he does the 'OK' hand gesture.
Answer: I'm not sure if this is the one you're thinking of, but an episode of "Ray Bradbury Theatre," called "A Sound of Thunder," dealt with a similar matter: a group of hunters travel back in time to hunt dinosaurs, only to find things have changed when they get back because someone stepped on a butterfly.
Xofer