Audio problem: When Homer says "I need change for a dollar. I also need a dollar", his mouth doesn't match what he's saying. (00:07:25)
Audio problem: When Matt Groening is putting boxes of comic books into the Comics Bongo Group truck, he says "I'm so rich" but his mouth isn't moving. (00:04:40)
Answer: I'm not sure if this is the one you're thinking of, but an episode of "Ray Bradbury Theatre," called "A Sound of Thunder," dealt with a similar matter: a group of hunters travel back in time to hunt dinosaurs, only to find things have changed when they get back because someone stepped on a butterfly.
Xofer