The One With All The Rugby - S4-E15
Other mistake: When Ross first goes out to play rugby and goes into the scrum, just after Emily talks to the rest of the players, he jumps into the middle of the scrum where the ball should be. Instead, in the next shot, the rugby ball is to the far left of the shot, not in the actual scrum.
Answer: The statements that she's contradicting (that it is common, it happens to every guy, and it's not a big deal), are the things that a woman commonly says to a man who is suffering from erectile difficulty, typically to assuage his bruised ego. However, most men do not believe that these statements are true, as evidenced by Chandler's outburst. He's so caught up in the proof that women are lying about it that he gives himself away.
Rooster of Doom