The One With Ross' New Girlfriend - S2-E1
Other mistake: After Rachel takes the phone from Ross and hangs up on Julie, when she's sitting at the table there's a bottle of Evian water in front of Monica with part of its brand name covered - the letters "e" and "n" are whited out leaving "via" on the bottle.
Answer: The painting doesn't have a name, and if it does it is never mentioned in this episode.