The One With The Video Tape - S8-E4
Other mistake: In series 8, 'The One with the Videotape,' when they are watching Ross and Rachel on the TV and when Rachel (on the video) is discussing the invitations and how Monica didn't shut up about sending them, Chandler points at the TV and makes a kind-of confused face. A few minutes later, just before he says 'Did you do it on our invitations?' the same shot of him pointing and pulling a face comes up. (00:17:05)
Answer: The statements that she's contradicting (that it is common, it happens to every guy, and it's not a big deal), are the things that a woman commonly says to a man who is suffering from erectile difficulty, typically to assuage his bruised ego. However, most men do not believe that these statements are true, as evidenced by Chandler's outburst. He's so caught up in the proof that women are lying about it that he gives himself away.
Rooster of Doom