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Continuity mistake: When Constantine manages to get the mirror through the window he falls on his back. To the right on the screen a chair lies on the floor beside a dresser. A few shots later when it cuts to Constantine getting up we can see the chair has changed position as its back now covers the opening of the dresser. (00:08:15)
Answer: Sin for a good reason is still sin, and as Gabriel says earlier, you can't buy your way into Heaven. Real Catholic dogma, however, doesn't hold the mentally ill as condemned for committing suicide.
Greg Dwyer
Except Isabel wasn't mentally ill. She saw angels and demons just like Constantine did. It was her parents who believed she was mentally ill.
While suicide is a mortal sin, it's shown later (as in major plot point) that sacrificing yourself to save the world is a redeeming act.
Yes, but Constantine also said "My parents were normal. They did what most parents would do. They made it worse. You think you're crazy long enough, you find a way out" which could relate to Isabel losing her sanity in a way as well because of her family and how they saw her. The whole Isabel's sacrifice is added by the novelization but the movie is ambiguous about the suicide.
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Except Isabel wasn't mentally ill. She saw half breeds just like John did.
Sacrificing yourself for others isn't a sin.