Samantha the Dressmaker - S2-E22
Revealing mistake: When Samantha and Endora are in Paris reviewing models in dresses, the models are frozen because Samantha and Endora are not supposed to be in the dress shop. One of the models, instead of being frozen, is seen blinking her eye and moving slightly.
Answer: Larry had been telling Darrin what it means psychologically that Samantha gave the coat away. Larry said giving it away meant she's happy being married but if she liked the coat it means she desires to be single and carefree. So when Darrin sees the coat, he immediately thinks Samantha doesn't want to be married and the fact that she twitched it means (in his mind) she wants to be a single, carefree witch again.
Bishop73