Revealing mistake: In one of Pickett's charge scene the bayonets are obviously rubber.

Gettysburg (1993)
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Directed by: Ron Maxwell, Ronald F. Maxwell
Starring: Tom Berenger, Martin Sheen, Stephen Lang, Richard Jordan
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Sergeant 'Buster' Kilrain: Some of them, they load and load, they never fire. They just keep right on loading. Some of them come home with seven, eight bullets rammed up in the barrel, never fired a shot.
Trivia: During Pickett's charge, Armistead's brigade gets caught at a wooden fence. There is a close up of one of his aides rallying the men and getting shot. If you look closely you will see it's Ted Turner, who bankrolled the movie.
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Answer: Yes. After the 2nd Maine Infantry was disbanded, there were 120 men with 1-year of service left. They mutinied because they said they only agreed to fight under the 2nd Maine flag and the Army disagreed. So they were marched under guard to the 20th Maine, led by Chamberlain. Chamberlain was able to convince most of them to fight, even though he was ordered to shoot any who did not fight.
Bishop73
Is there a reason why a few of them refused to fight?
Yes. The same reason why they mutinied.