Other mistake: Considering how long the Prime Minister's car is parked outside in front of the only road into the school, where there is to be the school Christmas concert, it's surprising how many cars are still trying to find a parking space. Also, you can see that no cars are driving when Natalie gets out of the Prime Minister's car.
Continuity mistake: When Juliet and Mark are at his flat there is a tall metal self-standing hanging rack and a tall black art canister directly in front of certain canvases and frames. As Juliet inserts the video in the wide shot, the rack and canister are gone. Yet, in the next shot they are back. (00:52:45)
Natalie: Hello, David. I mean "sir." Shit, I can't believe I've just said that. Oh, and now I've gone and said "shit" - twice. I'm so sorry, sir.
Prime Minister: It's fine, it's fine. You could've said "fuck", and then we'd have been in real trouble.
Natalie: Thank you, sir. I did have an awful premonition that I was going to fuck up on the first day. Oh, piss it!
Trivia: Billy Bob Thornton agreed to appear in the movie without having seen the script. On the day of shooting he told director Richard Curtis that he was scared of Benjamin Disraeli's facial hair, and as such wouldn't be able to do the scene in Ten Downing Street because there was a picture of him on the wall. Curtis told him to keep his back to the picture throughout the scene, which he does, although you'll notice he looks quite nervous.
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Answer: It's because of the complications that Sarah was having with her troubled brother. Apart from that, who's to say they don't eventually get together?
Hamster ★
In the follow-up short film (the Red Nose Day special) we learn she eventually gets her happy ending with a man played by Patrick Dempsey.